Calculate the concentration of nitric acid in moles per litre in a sample which has a density, 1.41 g mL–1 and the mass per cent of nitric acid in it being 69%.


Given:

Density of nitric acid = 1.41 g/mol


Percentage of Nitric acid = 69%


69% of nitric acid signifies 69g of nitric acid dissolved in 100g of solvent.


Volume of nitric acid solution = [mass of solution]/ density of solution


= 100/1.41


= 70.922 ml


Number of moles of Nitric Acid = Mass of Nitric acid/ Molecular Mass of nitric acid


= 69/63


= 1.095 moles


Molarity, Mo



= 1092.5/70.92


= 15.404 M


≈ 15.4 M


Therefore, concentration of nitric acid is 15.4 mole/L.


13
3