Calculate the concentration of nitric acid in moles per litre in a sample which has a density, 1.41 g mL–1 and the mass per cent of nitric acid in it being 69%.
Given:
Density of nitric acid = 1.41 g/mol
Percentage of Nitric acid = 69%
69% of nitric acid signifies 69g of nitric acid dissolved in 100g of solvent.
Volume of nitric acid solution = [mass of solution]/ density of solution
= 100/1.41
= 70.922 ml
Number of moles of Nitric Acid = Mass of Nitric acid/ Molecular Mass of nitric acid
= 69/63
= 1.095 moles
Molarity, Mo
= 1092.5/70.92
= 15.404 M
≈ 15.4 M
Therefore, concentration of nitric acid is 15.4 mole/L.