Bromine and air take about 15 minutes to diffuse completely but bromine diffuses into a vacuum very rapidly. Why is this so?

If bromine gas is allowed to enter a gas jar containing a vacuum,

the red-brown colour instantly fills the jar


because there are no air molecules to collide with.


This shows that the bromine molecules are moving very fast. When bromine is added to a gas jar filled with air, the red-brown gas is seen to slowly diffuse through the air.


The many collisions between the bromine molecules


and the air molecules slow down the rate


at which the red-brown bromine gas fills the jar.


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