An ideal gas is taken from an initial state i to a final state f in such a way that the ratio of the pressure to the absolute temperature remains constant. What will be the work done by gas?
Given
Initial pressure Pi
Final pressure Pf
Initial temperature Ti
Final temperature Tf
It is given that
From ideal gas equation, we know
PV=nRT
Where V=volume of gas
R=gas constant
n= number of moles
applying ideal gas equation for both processes, we get
And
From equation (i), (ii) and (iii), we get
∴ Vi=Vf
We know that,
Work done = force ×displacement
Volume = area ×displacement
Therefore,
Work done=pressure × volume
Let change in the volume of system = ΔV = Vf-Vi
Pressure =P
Thus, work done by the gas
ΔW=PΔV=P (Vf-Vi) =0
∴ work done by the gas is zero.