An ideal gas is taken from an initial state i to a final state f in such a way that the ratio of the pressure to the absolute temperature remains constant. What will be the work done by gas?

Given


Initial pressure Pi


Final pressure Pf


Initial temperature Ti


Final temperature Tf


It is given that



From ideal gas equation, we know


PV=nRT


Where V=volume of gas


R=gas constant


n= number of moles


applying ideal gas equation for both processes, we get



And



From equation (i), (ii) and (iii), we get



Vi=Vf


We know that,


Work done = force ×displacement



Volume = area ×displacement


Therefore,


Work done=pressure × volume


Let change in the volume of system = ΔV = Vf-Vi


Pressure =P


Thus, work done by the gas


ΔW=PΔV=P (Vf-Vi) =0


work done by the gas is zero.


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