When KMnO4 solution is added to oxalic acid solution, the decolourisation is slow in the beginning but becomes instantaneous after some time because
The following reaction takes place:
5C2O42– + 2MnO4 – + 16H+→ 2Mn2+ + 8H2O + 10CO2
Here, KMnO4 is a reactant in the reaction which forms Mn2+ which acts as an auto-catalyst. The reaction is slow initially because MnO4- is getting converted to Mn2+ but once Mn2+ forms, the reaction becomes faster due to the catalytic action