(a)



(b)



(c)



The reactivity of aryl halides to nucleophilic substitution is extremely low due to the resonance stabilization of the benzene ring. The –Cl bond also acquires a partial double bond due to resonance. Presence of an electron withdrawing –NO2 group at ortho or para positions on the ring increases the reactivity of aryl halides. The presence of –NO2 at a closer position to the C—Cl makes the molecule more reactive. The order of reactivity from highest to lowest should be (b) > (c) > (a). The correct option is (iii).

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