Amongst the given set of reactants, the most appropriate for preparing 2° amine is _____.

• When condensation occurs between a primary amine and aldehyde or a ketone a new imine compound ( Schiff base)n is formed.


• The reduction of this N-substituted imine on reduction with H2/Pt or any other strong reducing agents gives secondary amines.



Among the other 3 options (i) 2° R—Br + NH3 (ii) 2° R—Br + NaCN followed by H2/Pt and (iv) 1° R—Br (2 mol) + potassium phthalimide followed by H3O+/heat do not necessarily form a secondary amine.

1