For a certain reaction large fraction of molecules has energy more than the threshold energy, yet the rate of reaction is very slow. Why?
The two most important conditions for a reaction to occur according to the collision theory are:
• Energy greater than activation energy.
• Proper orientation of reactant molecules at the time of collision.
The equation of the collision theory is given by
Rate = PzABe-Ea/RT
So when the reaction occurs then molecules that don’t have a proper orientation decreases the rate of a reaction.