In the titration of Mohr salt solution with KMnO4 solution, dilute H2SO4 is used to provide acidic medium. The titration gives unsatisfactory result when we use HCl in place of H2SO4. This is because.

As dilute sulfuric acid is ideal for redox titration because it is neither an oxidizing agent and nor a reducing agent. On the other hand, KMnO4 which is the indicator, oxidises HCl to Cl2 as HCl is a mild reducing agent. Due to which, the purpose of the experiment is not served. So, dilute sulphuric acid is used.

1