Which factor imparts crystalline nature to a polymer like nylon?

Nylon is a copolymer of the amino acid Glycine (H2N-CH2-COOH) and aminocaproic acid [H2N(CH2)5COOH]. Glycine and aminocaproic acid combine in the following way.


In this structure, one molecule of Nylon can join another by intermolecular H –bonding which is present between two terminal groups –C=O and –NH. Since intermolecular H –bonding is relatively strong, it can lead to close packing of chains that impacts the crystalline character of Nylon.


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