Write the structures of the isomers of alcohols with molecular formula C4H10O. Which of these exhibits optical activity?
C4H10O means the isomers have 4 carbon atoms and one –OH group with all the sigma bonds between the adjacent carbon atoms.
Structures of the isomers of alcohols with molecular formula C4H10O:
a)
Butan-1-ol
b)
Butan-2-ol
c)
2-Methylpropan-1-ol
d)
` 2-Methylpropan-2-ol
We know, optical activity is shown by the compounds having a chiral center or a carbon atom attached to the four different groups. They are capable of rotating the plane of polarized light.
Here, only Butan-2-ol exhibits optical activity because it has a chiral carbon atom.