What does the negative sign in the expression mean?

By convention, all standard electrode potentials are reduction potentials. A positive value suggests that the reduced form of the species is more stable than hydrogen gas and a negative value suggests that the hydrogen gas is more stable than the reduced form of species. Here, the reduced form (Zn) is not stable. It is difficult to reduce Zn2+ to Zn. So, the reverse is more likely to happen. Zn would rather get oxidized to Zn2+ and H+ will get reduced.

Thus, Zn is more reactive than Hydrogen.


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