For a given material, the energy and wavelength of characteristic X-rays satisfy

Higher the shell from where the electron is transitioning, higher will be the energy. So energy of Kβ transition is more than Kα . Energy is inversely promotional to wavelength. So, λ (Kα) > λ (Kβ) > λ (Kγ).
Mα is a transition of an electron from N shell to M shell and requires much less energy than Kα transition from L shell to K shell. Thus, in terms of wavelength, λ (Mα) > λ (Lα) > λ (Kα).

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