The relation between pressure exerted by an ideal gas (Pideal) and observed pressure (Preal) is given by the equation:

Pideal = Preal+


If pressure is taken in Nm-2, number of moles in mol and volume in m3, Calculate the unit of ‘a’.


What will be the unit of ‘a’ when pressure is in atmosphere and volume in dm3?


We have:

P ideal = P real+


Pideal– Preal=


Now, putting the value of units of pressure, volumes and n, we have





The unit of ‘a’ when the pressure is taken in Nm-2, number of moles in “mol” and volume in m3 is


Now, when pressure is in atmosphere and volume in dm3 than, the value of ‘a’ is:



a =


1