On the basis of crystal field theory explain why Co(III) forms paramagnetic octahedral complex with weak field ligands whereas it forms diamagnetic octahedral complex with strong field ligands.

Weak field ligands do not cause much crystal field splitting, so the crystal field splitting energy is lesser than pairing energy ( ∆o<P ). Since pairing energy is higher than crystal field splitting energy, the electron will prefer not to pair up, therefore they will form paramagnetic(have unpaired electrons) octahedral complexes but for strong-field ligands, pairing of electrons is preferred because pairing energy is lower than crystal field splitting energy(∆o>P). A route where lesser energy is spent will always be preferred because the complex will be more stable in this case.


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