In an experiment, 4.90 g of copper oxide was obtained form 3.92 g of copper. In another experiment, 4.55 g of copper oxide gave, on reduction, 3.64 g of copper. Show with the help of calculations that these figures verify the law of constant proportions.

According to question-

Reaction 1-




So, 1 equivalent of Cu reacts with 0.25 equivalent of O2 to form 1.25 equivalent of copper oxide.


Reaction 2-




Here again, one can see that 1.25 equivalent of CuO decomposed to form 1 equivalent of Cu and 0.25 equivalent of oxygen.


Hence, law of constant proportion is verified.


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