A hydrogen atom initially in the ground level absorbs a photon, which excites it to the n = 4 level. Determine the wavelength and frequency of photon.

For ground level: n1 =4

Energy for the ground level of hydrogen atom, E1 = -13.6/n12


Substituting the value, we get


E1 = -13.6/12 = -13.6 eV


When the hydrogen atom is excited to n2= 4, then the energy absorbed by the photon is given as:


E2 = -13.6/42


E2= -13.6/16


The energy absorbed by the photon can be calculated by the following:


E = E2- E1


Or, E = (-13.6/16)- (-13.6/1)


On calculating, we get


E = 12.75 eV


In Joules, Energy is = 12.75 × 1.6 × 10-19 Joules


Or E = 2.04 × 10-18 J


Energy is given by the relation, E =hc/λ


Or λ = hc/E


Where h is Planck’s constant and is equal to 6.64 × 10-34 Js


c is speed of light and is equal to 3.0 × 108 m/s


substituting the values we get



On calculating, we get


λ = 9.7 × 10-8 m


or λ = 97 nm


Frequency can be calculated as follows:


v = c/λ


substituting the values, we get



v= 3.1 × 1015 Hz


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