A hydrogen atom initially in the ground level absorbs a photon, which excites it to the n = 4 level. Determine the wavelength and frequency of photon.
For ground level: n1 =4
Energy for the ground level of hydrogen atom, E1 = -13.6/n12
Substituting the value, we get
E1 = -13.6/12 = -13.6 eV
When the hydrogen atom is excited to n2= 4, then the energy absorbed by the photon is given as:
E2 = -13.6/42
E2= -13.6/16
The energy absorbed by the photon can be calculated by the following:
E = E2- E1
Or, E = (-13.6/16)- (-13.6/1)
On calculating, we get
E = 12.75 eV
In Joules, Energy is = 12.75 × 1.6 × 10-19 Joules
Or E = 2.04 × 10-18 J
Energy is given by the relation, E =hc/λ
Or λ = hc/E
Where h is Planck’s constant and is equal to 6.64 × 10-34 Js
c is speed of light and is equal to 3.0 × 108 m/s
substituting the values we get
On calculating, we get
λ = 9.7 × 10-8 m
or λ = 97 nm
Frequency can be calculated as follows:
v = c/λ
substituting the values, we get
v= 3.1 × 1015 Hz