Define conductivity and molar conductivity of the solution of an electrolyte. Discuss their variation with concentration.
The conductivity of a solution is defined as the conductance of one unit volume of solution kept between two platinum electrodes with a unit area of cross-section and at a distance of unit length.
The molar conductivity of the solution is defined as the conducting power of all the ions produced by one gram mole of an electrolyte in a solution. It is denoted by ∧m.
The conductivity of a solution (both for strong and weak electrolytes) always decreases with the decrease in concentration of the electrolyte i.e., on dilution. This pattern is seen because the number of ions per unit volume that carry the current in the solution decreases on dilution. The molar conductivity of the solution increases with the decrease in concentration of the electrolyte. This is because both the number of ions as well as mobility of ions increase with dilution.