Sucrose decomposes in acid solution into glucose and fructose according to the first order rate law, with t1/2 = 3.00 hours. What fraction of sample of sucrose remains after 8 hours?
t1/2 = 3.00 hours
We know, t1/2 = 0.693/k
∴ k = 0.693/3
k = 0.231hrs-1
We know, time
Where, k- rate constant
[R]° -Initial concentration
[R]-Concentration at time ‘t’
Thus, substituting the values,
log([R]0/[R]) = 0.8
log([R]/[R]0) = -0.8
[R]/[R]0 = 0.158
Hence, 0.158 fraction of sucrose remains.