Draw the structures of all isomeric alcohols of molecular formula C5H12O and give their IUPAC names.
The structures of all isomeric alcohols of C5H12O are given below:
(a)
Naming is done by the conventional method. The -OH group is attached on the first carbon.
(b)
3-Methylbutan-1-ol
Butane is the longest chain and methyl is the substituent group.
(c)
3-Methylbutan-1-ol
Longest chain is butane and conventional naming method is used.
(d)
2,2-Dimethylpropan-1-ol
Isomer is made by transforming the principal carbon into tertiary type. The longest chain is butane and named accordingly.
(e)
Pentan-2-ol
Longest chain is pentane and the numbering is chosen from the minimum position.
(f)
3-Methylbutan-2-ol
Butane is the longest chain, further numbering is done by choosing a minimum position for the -OH group followed by other substituents.
(g)
Pentan-3-ol
Conventional method of naming is used.
(h)
2-Methylbutan-2-ol
Butane is the longest chain and substituents are named accordingly by looking into minimum position.