Calculate the total pressure in a mixture of 8 g of dioxygen and 4 g of dihydrogen confined in a vessel of 1 dm3 at 27°C. R = 0.083 bar dm3 K–1 mol–1.
Given:
Mass of dioxygen= 8 g
Mass of dihydrogen= 4 g
Now, molar mass of dioxygen = 32g
Thus, number of moles of dioxygen = 8/32 = 0.25 mole
Also, molar mass of dihydrogen = 2g
Thus, number of moles of dihydrogen = 4/2 = 2 mole
Therefore, total number of moles in the mixture:
= 0.25 + 2 = 2.25 mole
Given: -
V = volume = 1 dm3,
n = number of moles = 2.25 mol
R = universal gas constant = 0.083 bar dm3 K-1 mol-1
T = temperature = 27°C = 300 K
Let the total pressure be P.
From ideal gas equation we know that -
PV = nRT
= 56.025 bar.
Hence, total pressure of the mixture is 56.025 bar.