Calculate the total pressure in a mixture of 8 g of dioxygen and 4 g of dihydrogen confined in a vessel of 1 dm3 at 27°C. R = 0.083 bar dm3 K1 mol1.

Given:

Mass of dioxygen= 8 g


Mass of dihydrogen= 4 g


Now, molar mass of dioxygen = 32g


Thus, number of moles of dioxygen = 8/32 = 0.25 mole


Also, molar mass of dihydrogen = 2g


Thus, number of moles of dihydrogen = 4/2 = 2 mole


Therefore, total number of moles in the mixture:


= 0.25 + 2 = 2.25 mole


Given: -


V = volume = 1 dm3,


n = number of moles = 2.25 mol


R = universal gas constant = 0.083 bar dm3 K-1 mol-1


T = temperature = 27°C = 300 K


Let the total pressure be P.


From ideal gas equation we know that -


PV = nRT




= 56.025 bar.


Hence, total pressure of the mixture is 56.025 bar.


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