At a certain temperature and total pressure of 105Pa, iodine vapour contains 40% by volume of I atoms

I2 (g) 2I (g)


Calculate Kpfor the equilibrium.

Kp value at equilibrium for reaction,

I2 (g) 2I (g)


is given as,



Given, 40% volume is occupied by I atoms.


60 % volume is occupied by I2.


Let V be total volume, then volume occupied by I and I2 are 0.4V and 0.6V respectively.


Partial pressure of I2 = (60/100) × 105 = 60 kPa


Partial pressure of I = (40/100) × 105 = 40 kPa


Substituting in equation for Kp,


Kp = = 2.67 × 104 KPa


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