At a certain temperature and total pressure of 105Pa, iodine vapour contains 40% by volume of I atoms
I2 (g) ⇌2I (g)
Calculate Kpfor the equilibrium.
Kp value at equilibrium for reaction,
I2 (g) ⇌2I (g)
is given as,
Given, 40% volume is occupied by I atoms.
∴ 60 % volume is occupied by I2.
Let V be total volume, then volume occupied by I and I2 are 0.4V and 0.6V respectively.
Partial pressure of I2 = (60/100) × 105 = 60 kPa
Partial pressure of I = (40/100) × 105 = 40 kPa
Substituting in equation for Kp,
Kp = = 2.67 × 104 KPa