Ionic product of water at 310 K is 2.7 × 10–14. What is the pH of neutral water at this temperature?
Given:
Ionic product of water(Kw) = 2.7 × 10–14
As we know that Kw = [H+][OH-]
For neutral water [H+]=[OH-]
∴ Kw = [H+][H+]
⇒[H+]2 = 2.7 × 10–14
⇒[H+] =
⇒[H+] = 1.643 × 10–7
Since, pH= -log[H+]
⇒pH = -log (1.643 × 10–7)
⇒pH = -log 1.643 + 7log 10
⇒pH = 7- 0.1256
⇒pH = 6.78
Thus, the pH of the neutral water is 6.78