Ionic product of water at 310 K is 2.7 × 10–14. What is the pH of neutral water at this temperature?

Given:

Ionic product of water(Kw) = 2.7 × 10–14


As we know that Kw = [H+][OH-]


For neutral water [H+]=[OH-]


Kw = [H+][H+]


[H+]2 = 2.7 × 10–14


[H+] =


[H+] = 1.643 × 10–7


Since, pH= -log[H+]


pH = -log (1.643 × 10–7)


pH = -log 1.643 + 7log 10


pH = 7- 0.1256


pH = 6.78


Thus, the pH of the neutral water is 6.78


66