While sulphur dioxide and hydrogen peroxide can act as oxidising as well as reducing agents in their reactions, ozone and nitric acid act only as oxidants. Why?

In sulphur dioxide(SO2), the oxidation number(O.N.)of S is + 4 and the range of the O.N. that s can have is from + 6 to -2.


Therefore, SO2 can act as an oxidizing as well as a reducing agent.


Let the oxidation number of S in SO2 be x.


X + 2(-2) = 0 {O.N. of O = -2}


X = + 4


In hydrogen peroxide (H2O2), the O.N. of O is -1 and the range of the O.N. that O can have is from 0 to -2. O can sometimes also attain the oxidation numbers + 1 and + 2.


Hence, H2O2 can act as an oxidizing as well as a reducing agent.


Let the oxidation number of O in H2O2 be x.


2(+ 1) + 2x = 0 {O.N. of H = + 1}


X = -1


In ozone(O3), the O.N. of O is zero and the range of the O.N. that O can have is from 0 to -2. Therefore, the O.N. of O can only decrease in this case. Hence, O3 can act only as an oxidant.


In nitric acid(HNO3), the O.N. of N is + 5 and the range of the O.N. that N cam have is from + 5 to -3. Therefore, the O.N. of N can only decrease in this case. Hence, HNO3 acts only as an oxidant.


Let the O.N. of N in HNO3 be ‘x’.


1 + x + 3(-2) = 0 {O.N. of H = + 1 and of O = -2}


X = + 5


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