Dumas method

kjeldahl’s method

1. In Dumas method, a known quantity of nitrogen containing organic compound is heated strongly with excess of copper oxide in an atmosphere of carbon dioxide to produce free nitrogen in addition to carbon dioxide and water.

1. In kjeldahl’s method,a known quantity of nitrogen containing organic compound is heated with conc. Sulphuric acid.

2. In Dumas method, a known quantity of nitrogen containing organic compound is heated strongly with excess of copper oxide in an atmosphere of carbon dioxide to produce free nitrogen in addition to carbon dioxide and water. The chemical equation of the process is

CxHyNz +(2x+y/2)CuO →xCO₂+ y/2 H₂O + z/2 N₂ +(2x+y/2)Cu

3. The nitrogen present in the compound is quantitatively converted into ammonium sulphate. It is then distilled with excess of sodium hydroxide. The ammonia evolved during this process is passed into a known volume of H₂SO₄.

The chemical equation in the process are

(NH₄)₂SO₄+2NaOH →Na₂SO₄+2NH₃+2H₂O

4. The traces of nitrogen oxides can also be produced in the reaction, which can be reduced to dinitrogen by passing the gaseous mixture over a heated copper gauge. The dinitrogen produced is collected over an aqueous solution solution of potassium hydroxide. The volume of nitrogen produced is then measured at room temperature and atmospheric pressure.

The acid that is left unused is estimated by volumetric analysis (titrating it against a standard alkali) and the amount of ammonia produced can be determined. Thus, the % of nitrogen in the compound can be estimated. This method cannot be applied to the compounds containing nitro and azo groups.